Total synthesis of epothilones using functionalised allylstannanes for remote stereocontrol
β Scribed by Martin, Nathaniel; Thomas, Eric J.
- Book ID
- 118035341
- Publisher
- Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 290 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1477-0520
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π SIMILAR VOLUMES
The relative configurations of 1,8-stereogenic centres can be controlled by coupling the tin(IV) chloride promoted reactions of aldehydes with 4-alkoxypent-2-enylstannanes, which proceed with excellent 1,5-induction, with an Ireland-Claisen rearrangement: this approach has been used to complete a di
The relative configurations of 1,8-stereogenic centres can be controlled by coupling the tin(IV) chloride promoted reactions of aldehydes with 4-alkoxypent-2-enylstannanes, which proceed with excellent 1,5-induction, with a 2,3-Wittig rearrangement: this approach has been used to complete a diastere