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Total synthesis of (.+-.)-damsin

✍ Scribed by De Clercq, P.; Vandewalle, M.


Book ID
126417041
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
638 KB
Volume
42
Category
Article
ISSN
0022-3263

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The total synthesis of (.+-.)-damsin
✍ Kretchmer, Richard A.; Thompson, Wayne J. πŸ“‚ Article πŸ“… 1976 πŸ› American Chemical Society 🌐 English βš– 236 KB
A facile entry to pseudoguaianes. Total
✍ Peter T. Lansbury; Algirdas K. Serelis πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 207 KB

Among the various classes of sesquiterpene a-methylene-y-butyrolactones, the pseudoguaianolides' are unparalleled as structural and stereochemical challenges2 to the discriminating synthetic organic chemist. I II III We herein report an extremely facile pseudoguaiane construction of potential value