Total synthesis of chromomoric acid B and F methyl esters
β Scribed by Xin-Jie Chu; Hong Dong; Zhi-Yu Liu
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 458 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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Stereospecific total synthesis of chromomoric acid C-I and C-II methyl esters and delicate elucidation of their structures have been reported. A stereospecific five-step synthesis, starting from enone 5, with one-pot threecomponent coupling and retro Diels-Alder reaction as the key reactions provide
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Natural Products Synthesis by Retro Diels-Alder Reaction. Part 16. Total Synthesis and Structural Revision of Chromomoric Acid D-I Methyl Ester. -The first total synthesis of chromomoric acid D-1 methyl ester (XII) is presented. The synthesis includes the addition of organolithium reagent (II) to ep