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Total synthesis of carbohydrates: stereoselective syntheses of 2,6-dideoxy-D-arabino-hexose and 2,6-dideoxy-D-ribo-hexose

✍ Scribed by Roush, William R.; Brown, Richard J.


Book ID
126140984
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
425 KB
Volume
47
Category
Article
ISSN
0022-3263

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2-Deoxy-D-arabino-[6-13C]hexose (10), to be used to test the stability of 2-deoxy-D-arabino-hexose 6-phosphate in brain tissue, was prepared. 2-Deoxy-D-arabino-hexose was labeled at C-6 because of the large difference in chemical shift between C-6 in the free sugar and C-6 in the 6-phosphate. The sy