Total synthesis of carbohydrates: stereoselective syntheses of 2,6-dideoxy-D-arabino-hexose and 2,6-dideoxy-D-ribo-hexose
β Scribed by Roush, William R.; Brown, Richard J.
- Book ID
- 126140984
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 425 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
bcnzyllactaldzhydc Icd 10 various 3,4,5-trioxygenatcd 1-hcxenes or w c i h i m . xylo. riho. and Iyxo configuration. The cxtcnt of asymrnctric induction wnnunted to 82: 18 (urahinoJxylo) in the addition ciC 3 and tn 4O:M) ( r i / w / / y . w ) on addition of 6. The factors which tlc!crininc thc dirc
2-Deoxy-D-arabino-[6-13C]hexose (10), to be used to test the stability of 2-deoxy-D-arabino-hexose 6-phosphate in brain tissue, was prepared. 2-Deoxy-D-arabino-hexose was labeled at C-6 because of the large difference in chemical shift between C-6 in the free sugar and C-6 in the 6-phosphate. The sy