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Total synthesis of bengamide E

✍ Scribed by Wenming Liu; Joanna M Szewczyk; Liladhar Waykole; Oljan Repič; Thomas J Blacklock

Book ID
104250449
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
69 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

A total synthesis of bengamide E is reported. The synthesis includes the utilization of D-tartrate as the chiral building block, construction of the E-olefin by the Julia protocol, an anti-aldol reaction to generate C-2 and C-3 stereocenters, and coupling of the thioester with caprolactam hydrochloride using sodium 2-ethylhexanoate.

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ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of Bengamide E.
✍ Wenming Liu; Joanna M. Szewczyk; Liladhar Waykole; Oljan Repic; Thomas J. Blackl 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

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