𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Total synthesis of (+)- and (-)-CPI-CDPI2: (+)-(3bR,4aS)- and (-)-(3bS,4aR)-deoxy-CC-1065

✍ Scribed by Boger, Dale L.; Coleman, Robert S.


Book ID
126329387
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
570 KB
Volume
53
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Total Synthesis of (±)-3-Deoxy-7,8-dihyd
✍ Fu-Lian Hsu; Kenner C. Rice; Arnold Brossi 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 911 KB

## Abstract A total synthesis of racemic 3‐deoxy‐7,8‐dihydromorphine ((±)‐**2**) and 4‐me‐thoxy‐ALmethylmorphinan‐6‐one ((±)‐**3**) is described. The key intermediate was 2,4‐dihydroxy‐__N__‐formylmorphinan‐6‐one **(11)**, obtained from 3,5‐dibenzyloxy‐phenylacetic acid **(4)** in 41.8% overall yie