Total synthesis of ageliferin via acyl N-amidinyliminium ion rearrangement
β Scribed by Ding, Hui ;Roberts, Andrew G. ;Harran, Patrick G.
- Book ID
- 120489128
- Publisher
- The Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 405 KB
- Volume
- 4
- Category
- Article
- ISSN
- 2041-6520
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A total synthesis of racemic a-allokainic acid is described, which starts from allylsilane 8 and methoxy-or chloroglycine derivative 9, and proceeds fully stereoselectively in nine steps and 1.1% overall yield. Key steps are the intermolecular N-acyliminium ion coupling of 8 with 9 and an intramolec
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