✍ Scribed by Frederic Cachoux; Malika Ibrahim-Ouali; Maurice Santelli
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A simple and highly efficient stereoselective total synthesis of (11__β__)‐11‐methoxycurvularin (**5**), a polyketide natural product, was achieved. The synthesis commenced with a Cu‐mediated regioselective opening of (2__S__)‐2‐methyloxirane (**6**) and comprised a __Keck__ asymmetric
The 2- and 6-methoxy derivatives of 8-aminoquinoline, as well as 5-aminoisoquinoline, condensed with 2-ethoxycarbonylcyclopentanone to give tricyclic intermediates in 86-90% yield. These secosteroids were cyclized in 35-69% yield with polyphosphoric acid to 2-methoxy-1,11-diaza-, 7-methoxy-1,11-diaz
## Abstract The sesquiterpenoid (+)‐myomontanone (2), a toxic component of the Australian plant __Myoporum montanum__, has been synthesized through a short efficient sequence. An electrochemical oxyselenation‐deselenation sequence allows oxidation of an intermediate olefin, in the presence of the f