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Total Synthesis and Revision of C6 Stereochemistry of (+)-Amphidinolide W (I).

✍ Scribed by Arun K. Ghosh; Gangli Gong

Publisher
John Wiley and Sons
Year
2006
Weight
11 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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Amphidinolide E (1) is a unique 18-membered macrolide isolated from the Y-5' strain of the dinoflagellate Amphidinium sp. [1] It exhibits cytotoxic activity against L1210 (IC 50 = 2.0 mg mL Γ€1 ) and L5178Y (IC 50 = 4.8 mg mL Γ€1 ) murine leukemia cells in vitro. Owing to its unique structural feature