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Total syntheses of naturally occurring spermidine alkaloids: (+)-(2S)-dihydromyricoidine and (+)-(2S)-myricoidine

✍ Scribed by Ursula A. Häusermann; Manfred Hesse

Book ID
104258513
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
196 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The spermidine alkaloids (+)-(2S)-dihydromyricoidine ( 5) and (+)-(2S)-myricoidine (4) were synthesized under asymmetric conditions. The synthetic compounds 4 and 5 were found to have positive 21

[O~]D values in both cases, which agrees with those of the natural alkaloids. Therefore the absolute configuration of the natural products are (2S)-configurated and not (2R)-as reported in the literature.

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