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Total Syntheses of Hyacinthacine A2 and 7-Deoxycasuarine by Cycloaddition to a Carbohydrate Derived Nitrone.

โœ Scribed by Francesca Cardona; Enrico Faggi; Francesca Liguori; Martina Cacciarini; Andrea Goti


Book ID
101945126
Publisher
John Wiley and Sons
Year
2003
Weight
17 KB
Volume
34
Category
Article
ISSN
0931-7597

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Total syntheses of hyacinthacine A2 and
โœ Francesca Cardona; Enrico Faggi; Francesca Liguori; Martina Cacciarini; Andrea G ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Practical syntheses of nitrone 8 by two different approaches from sugars are reported. Its use as a versatile intermediate in highly selective 1,3-dipolar cycloaddition reactions constitutes the key step for novel total syntheses of hyacinthacine A 2 (3) and 7-deoxycasuarine (20) by simple transform