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Total Syntheses of Cladoacetals A and B: Confirmation of Absolute Configurations

✍ Scribed by Hsu, Day-Shin; Lin, Shih-Chung


Book ID
127265592
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
780 KB
Volume
77
Category
Article
ISSN
0022-3263

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## Abstract Starting from 4,4‐dimethyl‐2‐cyclohexenone, an enantioselective synthesis of (–)‐isopisiferin has been accomplished in 15 steps with an overall yield of 11.4 %. This work not only provides synthetic evidence for confirming the absolute configuration of natural isopisiferin itself, but a