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Total Syntheses and Structural Revision of α- and β-Diversonolic Esters and Total Syntheses of Diversonol and Blennolide C

✍ Scribed by K. C. Nicolaou; Ang Li

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
375 KB
Volume
47
Category
Article
ISSN
0044-8249

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A Unified Strategy for the Asymmetric To
A Unified Strategy for the Asymmetric Total Syntheses of Diversonol and Lachnone C
✍ Dipl.-Chem. Manuel C. Bröhmer; Dr. Emmanuel Bourcet; Dr. Martin Nieger; Prof. Dr 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 320 KB 👁 2 views

## Abstract A unified synthetic strategy for the asymmetric syntheses of the natural products diversonol and lachnone C was developed by using the domino vinylogous aldol–oxa‐Michael reaction as the enantioselective key step. Further transformations include dihydroxylation, lactol‐opening by a Witt