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Total stereospecific synthesis of cis-chrysanthemic methyl ester : the cyclopropenic way.

โœ Scribed by M. Franck-Neumann; C. Dietrich-Buchecker

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
251 KB
Volume
21
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Bycy~oaddctcon 06 f-duzzopopaneto caob&w@po~o&cmethy~ estti one ohta4nh .tluo *domphcc gem-d.un&hyl 3H-py&azo&b. BoM tiomm glue by phoXoCybti the une CyCeoprtopene whah can be beiZetiv&y hydhogended to cc6-chay~anXhem~~ methyL esaW~. -

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Table . Hydrosilylation of imines la-5a (2 mmol) in toluene (2 mL) with diphenylsilane (0.8 mL, 4 mmol) and the in situ catalyst IRh(cod)CIIZ/(-))-diop. No. Imine Rh :