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Total Asymmetric Synthesis of 5-Deoxy-5-thio- l -allose

✍ Scribed by Emery, Fabienne; Vogel, Pierre


Book ID
121264590
Publisher
Taylor and Francis Group
Year
1994
Tongue
English
Weight
522 KB
Volume
13
Category
Article
ISSN
0732-8303

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πŸ“œ SIMILAR VOLUMES


Synthesis of 3-amino-3-deoxy-5-thio-d-al
✍ Najim A.L. Al-Masoudi; Natiq J. Tooma πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 338 KB

The syntheses have been described of the 2-acetamido-2-deoxy derivatives of 5-thio-D-glucose lm3, 5-thio-D-mannose 4, 5-thio-D-allose 5, 3-acetamido-3-deoxy5thio-D-xylose6, and 4-acetamido-4-deoxy-5-thio-r\_-lyxose6. We now report the syntheses of 3-amino-3-deoxy-5-thio-D-allose hydrochloride and a

Synthesis of 5-thio-d-allose and the met
✍ Najim A.L. Al-Mosoudi; Neil A. Hughes πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 895 KB

ABSTRAm 5,6-Anhydro-1,2-0-isopropylidene-3-O-methanesulphonyl-a-~-idofuranose was converted, via the related gZucod$-episulphide, into 6-0-acetyl-5-S-acetyl-1,2-O-isopropylidene-3-O-methanesulphonyl-5-thio-at-D-glucofuranose (9). Replacement of the acetyl groups of 9, or the related 3-toluene-p-sulp

Synthesis of 6-deoxy-5-thio-d-glucose
✍ Γ‰va BozΓ³; SΓ‘ndor Boros; JΓ‘nos Kuszmann; Eszter GΓ‘cs-Baitz πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 834 KB

Three routes were investigated for the conversion of D-glucose into the title compound. In the first approach, reduction of the 5,6-thiirane ring of 5,6-dideoxy-5,6-epithio-1,2-O-isopropylidene-t~-D-glucofuranose (17) as well as that of its 3-O-allyl derivative (13) with lithium aluminium hydride wa