Torsional Coriolis coefficients in a ‘regular’ vibrational basis for molecules with one pair of internal rotors

An Analysis of Higher Order Vibration–To

An Analysis of Higher Order Vibration–Torsion–Rotation Interactions and Spectra for a Molecule with an Internal Rotor

✍ Yun-Bo Duan; Li Wang; Kojiro Takagi 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 461 KB

Motivated by attempts to answer the questions (i) if the same order of magnitude is really appropriate for the torsional angular momentum terms P ␥ 2 and the rotational angular momentum term P 2 (or P a 2), (ii) how to systematically analyze various higher order interaction effects, especially the t