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Torquoselectivity in the Cationic Cyclopentannelation of (2Z)-Hexa-2,4,5-trienal Acetals

✍ Scribed by Beatriz Iglesias; Angel R. de Lera; Jesús Rodríguez-Otero; Susana López


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
440 KB
Volume
6
Category
Article
ISSN
0947-6539

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Binding of the cationic 5-coordinate Zn(
✍ Vladimir S. Chirvony; Victor A. Galievsky; Sergei N. Terekhov; Boris M. Dzhagaro 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 246 KB

The localization of the water-soluble cationic porphyrin ZnTMpyP(4) [Zn(II) derivative of 5,10,15,20-tetrakis(4-N-methylpyridyl)porphyrin] in its complex with [poly(dG-dC)] 2 is studied as a function of the solution ionic strength ( ϭ 0.20 -0.03). It is shown that the position of the Soret band maxi