Topological Properties of the Born–Oppenheimer Approximation and Implications for the Exact Spectrum
✍ Scribed by Frédéric Faure; Boris Zhilinskii
- Book ID
- 110295529
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 235 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0377-9017
No coin nor oath required. For personal study only.
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## Abstract A new derivation of the Born–Oppenheimer separation of electronic and nuclear motion is presented. The arguments used differ from those in earlier works in not being specially designed for molecules. Instead they aim at an intuitive understanding of the qualitative behavior of the low e
## Abstract Theory is presented for determining the effects of band structure on electronic CD spectra. In this development, the effect of the first‐order correction to the Born‐Oppenheimer approximation is considered. This removes the unrealistic feature of identical CD and absorbance spectral ban