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Topological isomerism in a chiral handcuff catenane

✍ Scribed by Hartlieb, Karel J. ;Blackburn, Anthea K. ;Schneebeli, Severin T. ;Forgan, Ross S. ;Sarjeant, Amy A. ;Stern, Charlotte L. ;Cao, Dennis ;Stoddart, J. Fraser


Book ID
121206079
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
872 KB
Volume
5
Category
Article
ISSN
2041-6520

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The synthesis of a topologically chiral in,out-bis-sulfonamide catenane and its "dimer" are reported. The structures of the amide wheel and of the catenane were resolved by X-ray analysis. NMR-titration of the monosulfonamide-wheel yielded conclusive association constants supporting the proposed reg