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Tolanophane Revisited – Resolution and Racemization Mechanism of a Twisted Chiral Aromatic Compound

✍ Scribed by Shinji Toyota; Katsutoshi Kawai; Tetsuo Iwanaga; Kan Wakamatsu


Book ID
112082989
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
622 KB
Volume
2012
Category
Article
ISSN
1434-193X

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(S)-Leucine and [(S)-1-(1-Naphthyl)ethyl
✍ Anna Iuliano; Emanuele Attolino; Piero Salvadori 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB 👁 3 views

Two selectors derived from [(S)-1-(1-naphthyl)ethyl]amine and (S)-leucine have been chemically bonded to one another and the resulting chiral auxiliary linked covalently to silica gel, to produce a new chiral stationary phase (CSP) for the HPLC resolution of enantiomers. The CSP is able to separate