Aqueous solutions of hydrazine reduce strong oxidizing agents in dilute acid medium to give nitrogen, ammonia and hydrazoic acid. The nature and relative abundance of the oxidation products depend upon reaction conditions and the oxidanti. KIRK AND BROWNER have classified different oxidants as mono-
Titrimetric determination of thiocyanates with sulfatoceric acid
โ Scribed by Surjit Singh; Joseph R. Siefkel
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 355 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
โฆ Synopsis
~W3TRIBUTION COEFFICIENT 01; CUPFERRON 489 cupferron; clle cst basde sur la r6action color&c dc cc composd avec le pentacyanoamminofcrrate(II) de sodium. Unc valcur dc I.+Z a dt6 obtcnuc pour dcs solutions dans l'eau ct dans lc chloroformc, on milieux pcrchloriquc ct chlorhgdrique. Die Farbrcaktion dcs liupfcrrous mit Natriumpentacyano-ammiu-fcrrat-(11) wurde zur spcktrophotomctrischcn 13cstimmung dcs Vertcilungskoeffizicutcn clcs liul~fcrrons hcrangczogcn. Fiir die Vcrteilung zwischcn Chloroform und w%ssrigcr PcrchlorsZurc bczw. Salzs&wc wurdc clcr \Vcrt 8,'x'42 bci pH > 3 crhaltcn. StPrker saurc IAsungcn geben ticfcrc \Vcrtc. I,.
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A titrimetric method is described for the determination of several amino acids, namely, histidine, methionine, cystine, cysteine, and tryptophan. The method involves the use of 1,3-dibromo-5,5dimethylhydantoin or N-bromophthalimide as titrant. The equivalent point is detected directly, indirectly, p