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Titrimetric determination of thiocyanate and thiosulphate ions by oxidation with iodine in alkaline solution

โœ Scribed by R. Belcher; Sarah Sau-Tung Liao; Alan Townshend

Book ID
118992337
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
353 KB
Volume
23
Category
Article
ISSN
0039-9140

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Mechanistic studies with positive iodine
Mechanistic studies with positive iodine: Kinetics of oxidation of thiocyanate ion by iodine monochloride and aqueous iodine in perchloric acid medium
โœ B. Thimme Gowda; J. Ishwara Bhat ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 433 KB ๐Ÿ‘ 1 views

Kinetics of oxidation of thiocyanate ion (NCS-) by iodine monochloride and iodine has been studied in aqueous perchloric acid medium. The rates of oxidations followed the rate laws: Variations in ionic strength and dielectric constant of the medium had little effects on the rates of reactions with