Titration curves of compleximetric titrations of mixtures of metal ions with one ligand : Part I. Mathematical expressions

✍ Scribed by U. Hannema; G. Den Boef

• Book ID: 104103446
• Publisher: Elsevier Science
• Year: 1967
• Tongue: English
• Weight: 381 KB
• Volume: 39
• Category: Article
• ISSN: 0003-2670
• DOI: 10.1016/s0003-2670(01)80477-3

✦ Synopsis

Several papers have appeared which deal with calculations of titration curves m complcuimetrlc titrations I4 However, no exact mathematical cxprcssions 5ce.m to bc available for titrations of mixtures of two or more metal Ions with one ligand Such ezIpression5 would be of interest, not only to judge the possibilities for end-I)OlIIt dCtCLtlcJn at all, but also for the selection of the proper mdlcatlon method Exprcsslons arc dcrlvcd 1x1 this paper in which only two slmphflcatlons arc mtroduccd Ch,mgcs m volume arc ncglcctccl and conccntratlons arc usccl instead of actlvttlcs *P~cxpcrlnlental dctailv ~111 bc glvcn rn n subvequcnt paper .