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Titelbild: Catalytic Hydrogenation of Unsaturated Aldehydes on Pt(111): Understanding the Selectivity from First-Principles Calculations (Angew. Chem. 33/2005)

✍ Scribed by David Loffreda; Françoise Delbecq; Fabienne Vigné; Philippe Sautet

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 76 KB
Volume: 117
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200590110

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**The selective hydrogenation** of unsaturated aldehydes such as propenal on a Pt(111) surface, as shown in the cover picture, is an example of a heterogeneous catalysis reaction that yields two competitive products: propenol and propanal. The selectivity of this reaction is controlled by the balanc