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Titanium(IV) terminal hydroxo complexes containing chelating bis(phosphine oxide) ligands

✍ Scribed by Xiao-Yi Yi; Ian D. Williams; Wa-Hung Leung


Book ID
108189179
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
191 KB
Volume
691
Category
Article
ISSN
0022-328X

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Titanium(IV) and Zirconium(IV) Sulfato C
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## Abstract Treatment of titanyl sulfate in about 60 mM sulfuric acid with NaL~OEt~ (L~OEt~^βˆ’^=[(Ξ·^5^‐C~5~H~5~)Co{P(O)(OEt)~2~}~3~]^βˆ’^) afforded the μ‐sulfato complex [(L~OEt~Ti)~2~(μ‐O)~2~(μ‐SO~4~)] (2). In more concentrated sulfuric acid (>1 M), the same reaction yielded the di‐μ‐sulfato complex