Titanium(III)-Promoted Stereoselective Synthesis of Simple C -Glycosides
โ Scribed by Spencer, Roxanne P.; Schwartz, Jeffrey
- Book ID
- 127121135
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 152 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
A novel, highly stereoselective method for O-glycosylation of glycals and glycosylbromides is developed using orthoformates as acceptors in the presence of InCl 3 to afford the corresponding O-glycopyranosides in 66-94% yield. Both perbenzyl and peracetyl glycals afford the corresponding 2,3-unsatur
AbstractรTitanocene(III) chloride and zirconcene(III) chloride are effective and mild reagents for radical generation in organic synthesis. In carbohydrate chemistry, these species are useful for the conversion of glycosyl halides to glycals, and for the stereospeciยฎc preparation of C-glycosides. In
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