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Titanium-induced conjugated addition of the fluorenone dianion to α, β-enones.

✍ Scribed by Jean-Marc Pons; Maurice Santelli

Book ID
104219762
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
206 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cross-coupZzng of fZuore;one and enones wcth TzCL4-Mg led to y-ketoi! derzvatzves

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Reaction of indoles with electron deficient olefins under the influence of bismuth triflate has been studied at ambient temperature and affords the corresponding 3-alkylated indoles in excellent yields.