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Titanium Alkoxides as Initiators for the Controlled Polymerization of Lactide

✍ Scribed by Kim, Youngjo; Jnaneshwara, G. K.; Verkade, John G.


Book ID
120199066
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
168 KB
Volume
42
Category
Article
ISSN
0020-1669

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Catalytic ring-opening polymerization of
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Six different titanium biphenolate complexes were synthesized and investigated as initiators for the ring opening polymerization of l-lactide in the bulk phase but typically below the degradation temperature of the monomer. All the titanium complexes are effective in forming polylactide with good co