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Titanium Alkali Metal Nitrido Complexes

✍ Scribed by María García-Castro; Avelino Martín; Miguel Mena; Adrián Pérez-Redondo; Carlos Yélamos

Book ID: 101369599
Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 37 KB
Volume: 7
Category: Article
ISSN: 0947-6539
DOI: 10.1002/1521-3765(20010417)7:8<1585::aid-chem15851>3.0.co;2-6

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## Abstract Several heterometallic nitrido complexes have been prepared from the reaction of the trinuclear imido‐nitrido titanium complex [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) with cadmium and mercury derivatives. Treatment of 1 with cadmium dichloride or cadmium diiodide in toluene afforded