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Tin(II) amides: new reagents for the conversion of esters to amides

โœ Scribed by Wang, Wei Bo; Roskamp, Eric J.


Book ID
118739247
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
328 KB
Volume
57
Category
Article
ISSN
0022-3263

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โœ Wei-Bo Wang; Josรฉ A. Restituyo; Eric J. Roskamp ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 267 KB

We have developed two new procedmea for the dtrect converston of e&are to secondary am&b. In our first procedure, secondary amides can be prepared in 8348% yield starting from glycol esters. Addition of Sn[NU'MS)~2 and a primary amine to the glycol ester generates an intermediate tin(III alkoxy amid

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