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Tin-Free Radical Addition of Acyloxymethyl to Imines

✍ Scribed by Yamada, Ken-ichi; Nakano, Mayu; Maekawa, Masaru; Akindele, Tito; Tomioka, Kiyoshi

Book ID
120322610
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
97 KB
Volume
10
Category
Article
ISSN
1523-7060

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Benzyl radical is added regioselectively to the carbonΒ±nitrogen double bond of aromatic imines by UV irradiation (l>300 nm) of a ternary mixture of benzyl bromide/aromatic imines/1-benzyl-1,4-dihydronicotinamide (BNAH) in acetonitrile via a BNAH-mediated photoinduced electron transfer mechanism.