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Time series: a complementary technique to control charts for monitoring analytical systems

✍ Scribed by M.Pilar Callao; A. Rius


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
207 KB
Volume
66
Category
Article
ISSN
0169-7439

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✦ Synopsis


In this study, the time series method was used as a complement to the most common control charts (X and R charts) to monitor a sequential injection analysis (SIA) system with UV/visible detection for determining sulphates in water.

Time series confirm the most important results of control charts and provide better understanding of how the system behaves over time. They provide information about the possible relationship between one datum and the previous data in the series. This opens up more realistic possibilities if an out-of-control point has to be substituted (once what has caused it is known) or if some missing data have to be evaluated. They also provide information for reducing the frequency of the analysis, if this proves necessary, and for avoiding autocorrelation in the data.


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In this tutorial, the techniques used to study the reliability of analytical systems over time are discussed. The most classi-Ε½ . cal approach is to use statistical process control SPC with control charts, and its principal characteristics, benefits and limi-Ε½ . tations are shown. The advanced proce