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Time-resolved resonance Raman (TR3) spectroscopy. structural identification of an intermediate in the photolysis of trans-stilbene dianions

✍ Scribed by L.R. Dosser; J.B. Pallix; G.H. Atkinson; H.C. Wang; G. Levin; M. Szwarc

Book ID: 107732106
Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 511 KB
Volume: 62
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80762-9

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## Abstract We report time‐resolved resonance Raman spectra for the azirine intermediate produced in the 2‐fluorenylnitrene ring‐expansion reaction to form a dehydroazepine product. The Raman bands obtained with a 252.7 nm probe wavelength and 500 ns delay time exhibit reasonable agreement with pre