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Time-Resolved Resonance Raman Observation of the 2-Fluorenylnitrenium Ion Reaction with Guanosine to Form a C8 Intermediate

✍ Scribed by Chan, Pik Ying; Kwok, Wai Ming; Lam, Sze Kui; Chiu, Pauline; Phillips, David Lee

Book ID
127323170
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
57 KB
Volume
127
Category
Article
ISSN
0002-7863

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Time-Resolved Resonance Raman and Densit
Time-Resolved Resonance Raman and Density Functional Study of an Azirine Intermediate in the 2-Fluorenylnitrene Ring-Expansion Reaction To Form a Dehydroazepine Product
✍ Shing Yau Ong; Peizhi Zhu; King Hung Leung; David Lee Phillips πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 168 KB πŸ‘ 1 views

## Abstract We report time‐resolved resonance Raman spectra for the azirine intermediate produced in the 2‐fluorenylnitrene ring‐expansion reaction to form a dehydroazepine product. The Raman bands obtained with a 252.7 nm probe wavelength and 500 ns delay time exhibit reasonable agreement with pre