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Time-Resolved Resonance Raman, Electron Spin Resonance, and ab Initio Molecular Orbital Study of the Structure and Proton Reactivity of 4-Carbamylpyridinyl Radicals †

✍ Scribed by Tripathi, G. N. R.; Su, Yali; Bentley, John; Fessenden, R. W.; Jiang, P.-Y.


Book ID
126786302
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
374 KB
Volume
118
Category
Article
ISSN
0002-7863

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An electron spin resonance study of the reaction of aliphatic amines and OH-with 4nitroveratrole (NV) in its lowest electronic triplet state is presented. It is concluded that both nucleophiles transfer an electron to triplet-state NV in the first chemical step of the reaction. This is then followed