Time-resolved resonance Raman and density functional theory study of the deprotonation reaction of the triplet state of para-hydroxybenzophenone in mixed acetonitrile/water solutions

Time-Resolved Resonance Raman and Densit

Time-Resolved Resonance Raman and Density Functional Study of an Azirine Intermediate in the 2-Fluorenylnitrene Ring-Expansion Reaction To Form a Dehydroazepine Product

✍ Shing Yau Ong; Peizhi Zhu; King Hung Leung; David Lee Phillips 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 1 views

## Abstract We report time‐resolved resonance Raman spectra for the azirine intermediate produced in the 2‐fluorenylnitrene ring‐expansion reaction to form a dehydroazepine product. The Raman bands obtained with a 252.7 nm probe wavelength and 500 ns delay time exhibit reasonable agreement with pre