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Time resolved powder neutron diffraction investigations of reactions of solids with water

✍ Scribed by A.Nørlund Christensen; H. Fjellvadotg; M.S. Lehmann


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
213 KB
Volume
16
Category
Article
ISSN
0008-8846

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✦ Synopsis


The reactions of brownmillerite (C4AF) with D20 as well as those of a mixture of CI2A 7 and CaSO4.2D20 with D20 were investigated by on-line powder neutron diffraction.

The crystalline reaction products in the hydrolysis of C4AF are Ca3A12(OD)12 and Ca(OD) 2. For the sulphate containing system a precursor phase was observed before the formation of deuterated ettringite,Ca6A12(OD)12(SO4)3.26D20.


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The TbRu 2Àx Pd x Si 2 series of solid solutions (0oxo2) was studied by powder X-ray and neutron diffraction, and by magnetometric methods. The investigated solid solutions crystallise in the body-centred tetragonal ThCr 2 Si 2 -type crystal structure (space group I4/mmm). The magnetic moments are l