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Time-resolved fluorescence from the 1Au state of glyoxal

✍ Scribed by J.T. Yardley; G.W. Holleman; J.I. Steinfeld


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
307 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis


tonable, dye lasers have been used to measure ciirectly the lifetime of the 'A, state of low pres-sLL'e glyoxalvapok A cohision-free Iifetirne of (2.16 :f 0.05) psec is obtained. Quenching as the result of molecular collisions with a variety of buffer gases is also studied, and quenching rate constants determined from Stern-Vobner plots are reported. Under low resolution'the collision-free Lifetime of glyoxal appears to be independent of wavelength over the range 45 10 A to 4585 A.


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