✦ LIBER ✦
Time-resolved absorption spectroscopic studies on the reaction of conformationally fixed o-(9-fluorenyl)phenylnitrenes
✍ Scribed by Shigeru Murata; Tadashi Sugawara; Nobuaki Nakashima; Keitaro Yoshihara; Hiizu Iwamura
- Book ID
- 104241330
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 232 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Laser-flash photolysis studies have been carried out on a solution of apand sp-9-(2-asido-4,6-dimethylphenyl)fluorenes (3) in methanol-ether at 25"C. The rates of formation of azanorcaradiene (5) from ap-nitrene (4)ap, and of 9-methoxyfluorene (7) from o-quinoid intermediate (6) were determined.