Time-domain measurements of vibrational relaxation at surfaces: CO(V=1) in metal carbonyl systems

Population relaxation of CO(v = 1 ) vibr

Population relaxation of CO(v = 1 ) vibrations in solution phase metal carbonyl complexes

✍ E.J. Heilweil; R.R. Cavanagh; J.C. Stephenson 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 791 KB

Picosecond infrared saturation-recovery experiments were performed to obtain measurements of the vibrational energy lifetimes ( r, ) of CO( v= 1) vibrations (Y GZ 1920-l 985 cm-' ) of carbonyl-containing metal complexes in dilute, room-temperature solutions. For relaxation of the F,, CO-stretching v