## An cltension of the time-dependent Hartree-Focii approximation to employ a multimnti~ur~ttin Ihrlree-Fock state as reference state has been devefoped-Preliminary multicontigxation time-dependent Hartree-Fock calculations wirh the round state of the Be atom using the configurations Is' and 7~' s
Time-dependent rotated hartree approach
β Scribed by J. Kucar; H.-D. Meyer; L.S. Cederbaum
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 587 KB
- Volume
- 140
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A new app~ximation for the solution of the tjme~e~ndent Schriidinger equation is proposed. It improves the time-dependent Hartree approximation by in&ding time-dependent unitary operators acting on the Hartree product. This makes it possible to describe the correlations between various degrees of freedom. The new approach is tested on a model of coupled oscillators showing good agreement with the exact results.
π SIMILAR VOLUMES
The time-dependent Hartree-Fock method for atomic collisions is described, together with associated numerical techniques. Some applications, chiefly to ion-atom collisions, are presented.