✦ LIBER ✦

Time dependence of the relaxation parameters in non-Debye solvents

✍ Scribed by W.Ronald Fawcett

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 600 KB
Volume: 199
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)80063-h

No coin nor oath required. For personal study only.

✦ Synopsis

Expressions for the time dependence of the longitudinal relaxation parameter for' solvents exhibiting two and three Debye relaxation processes are developed on the basis of the model of Hynes. These expressions are applied to dielectric relaxation data for the lower alcohols, the amides and other solvents which have been studied over a wide frequency range. The significance of the results obtained is discussed with respect to data for time-resolved fluorescence spectroscopy recently reported in the literature.

📜 SIMILAR VOLUMES

Influence of non-Debye relaxation and of

Influence of non-Debye relaxation and of molecular shape on the time dependence of the stokes shift in polar media

✍ Edward W. Castner Jr.; Graham R. Fleming; Biman Bagchi 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 599 KB

We present theoretical analyses of two different aspects ofthe time dependence of the fluorescence Stokes shift in polar liquids. We show that a small deviation from the Debye form for the dielectric relaxation of the solvent can strongly influence the time evolution of the Stokes shift. Using the D

Effects of non-Debye solvent relaxation

Effects of non-Debye solvent relaxation in electron transfer reactions: A numerical study

✍ Teresa Fonseca 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 532 KB

To assess the importance of the different time scales of non-Debye solvent relaxation on the reaction kinetics of electron transfer reactions we have performed a numerical simulation study for a model system of an activated solvent-controlled electron transfer reaction in the weakly adiabatic regime

Solvent dependence of vibrational freque

Solvent dependence of vibrational frequencies and relaxation times in dichloromethane

✍ S.J.H. Chen; M. Schwartz 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 493 KB

Picosecond solvation of electronically e

Picosecond solvation of electronically excited solutes in alcoholic solvents: non-debye behaviour of the time-dependent fluorescence shift related to h

✍ A. Declémy; C. Rullière; Ph. Kottis 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 780 KB

Solvent dependence of 13C relaxation tim

Solvent dependence of 13C relaxation times and reorientational dynamics in tribromobenzene

✍ A. F. T. Chen; S. P. Wang; M. Schwartz 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB

The "C spin-lattice relaxation times and nuclear Overhauser enhancements of protonated carbons in 1,3,5tribromobenzene were measured in a number of solvents of widely varying viscosity. Derived reorientational correlation times were found to increase approximately linearly with solution viscosity, a

Temperature dependence of the rotational

Temperature dependence of the rotational relaxation time in nitrogen

✍ Andrey E. Belikov; Ravel G. Sharafutdinov; Mikhail L. Strekalov 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 366 KB