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Time-averaged solution geometries for ligand-europium Complexes: The significance of functional group Rotation, basicity, and steric environment

✍ Scribed by P.V. Demarco; B.J. Cerimele; R.W. Crane; A.L. Thakkar


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
229 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis


Considerable evidence now exists to support the contention that chemical shifts induced in the pmr spectra of organic aliphatic ligands by paramagnetic lanthanide ions are predominantly pseudocontact in origin.lW4

Accordingly, lanthanide induced shifts (A&-values21 can be