Ti(iv)-amino triphenolate complexes as effective catalysts for sulfoxidation
β Scribed by Mba, Miriam; Prins, Leonard J.; Zonta, Cristiano; Cametti, Massimo; Valkonen, Arto; Rissanen, Kari; Licini, Giulia
- Book ID
- 120318315
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 496 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1477-9226
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The exchange reactions between Ti compounds and hexagonal mesoporous silicas (HMS) have been investigated in detail by means of UV-Vis diffuse reflection spectra, FT-IR, N 2 volumetric adsorption, chemical and elemental analyses. It was found that the exchange of titanium tetraisoproxide (Ti(O i Pr)
## Abstract The efficient catalytic oxidation of secondary amines to nitrones using hydrogen peroxide as primary oxidant is described. The titanium(IV) complex **2** bearing a __C__~3~βsymmetrical triphenolate amino ligand has proved to be an airβ and waterβtolerant complex that efficiently catalyz