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Thulium Alkylidene Complexes: Synthesis, X-ray Structures, and Reactivity

✍ Scribed by Cantat, Thibault; Jaroschik, Florian; Ricard, Louis; Le Floch, Pascal; Nief, François; Mézailles, Nicolas


Book ID
121477343
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
165 KB
Volume
25
Category
Article
ISSN
0276-7333

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The coordination behaviour of 2,6-disilyl-substituted characterized. The formation of 6 results from a [4 + 2] cycloaddition between one alkynyl group of each phosphinine phosphinines towards gold(I) has been examined. The reaction of the bis(trimethylsilyl)phosphinine 1 with [AuCl(SMe 2 )] gives wi