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Through-bridge electron transfer: A propagator study of a simple three-site model

✍ Scribed by Leslie J. Root; Mary Jo Ondrechen


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
377 KB
Volume
88
Category
Article
ISSN
0009-2614

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✦ Synopsis


Recewcd 22 hkuch 1982

Electron transfer m a model symmetncai bndged system A-B-A IS investigated using smgle-particle Green's functions.

The dependence of the rate of electron transfer and the degree of mstantaneous spatial delocahzation upon the energy of the bans orbital of the bndgmg species B. relative to the energy of the donor (and acceptor) species A, is investigated


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## Abstract We have tested the reference interaction site model (RISM) for the case of the hypernetted chain (HNC) and the partially linearized hypernetted chain (PLHNC) closures improved by a repulsive bridge correction (RBC) for ionic hydrated species. We have analyzed the efficiency of the RISM/