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Through-bond interaction of two mutually perpendicular .pi. systems. A comparison with spiroconjugation

✍ Scribed by Bischof, Peter; Gleiter, Rolf; Haider, Rudolf


Book ID
127175775
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
736 KB
Volume
100
Category
Article
ISSN
0002-7863

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Evidence for through-bond interaction be
✍ Rolf Gleiter; Rudolf Haider; Jens Spanget-Larsen; Peter Bischof πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 177 KB

Comparison of the photoelectron (PE) spectra of tetravinylmethane (1) and trans, trans, -trans-1,2,3,4-tetravinylcyclobutane (2) indicates that through-bond interaction in 2 is comparable in magnitude to the through-space Spiro interaction in 1. A similar result is obtained by comparison of the UV