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Three structural modifications in the series of layered solids T(H2O)2[Ni(CN)4]·xH2O with T = Mn, Co, Ni: Their nature and crystal structures

✍ Scribed by J. Rodríguez-Hernández; A.A. Lemus-Santana; C.N. Vargas; E. Reguera


Book ID
116389544
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
793 KB
Volume
15
Category
Article
ISSN
1631-0748

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.