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Three New Chiral Aminoethers from Tartaric Acid for Improved Asymmetric Syntheses with Organolithium Reactions. Preliminary communication

✍ Scribed by Dieter Seebach; Gerhard Crass; Eva-Maria Wilka; Don Hilvert; Edi Brunner


Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
153 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The chiral aminoethers 1–4, accessible from tartaric acid, are tested as complexing ligands in organolithium reactions. The tetramine 4 turns out to cause highest inductions [see Table 2 and Equations (1)–(4)].