Three-Coordinated Boron-11 Chemical Shifts in Borates
✍ Scribed by Kroeker, Scott; Stebbins, Jonathan F.
- Book ID
- 117995595
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 96 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Numerous alkenylsilanes with silyl and boryl groups in __cis__ ‐positions at the CC bond were studied for the first time by ^29^Si NMR with regard to isotope‐induced chemical shifts Δ^10/11^B(^29^Si). Such effects are transmitted across an Si—X—B bridge (X = H, OR, SR, Cl) most efficie
Nuclear Magnetic Resonance (NMR) chemical shifts(δ) for elements in solids may often be approached by ab initio cluster calculations. We employ this technique to investigate the influence of structural alterations on the 15 N and 11 B chemical shifts in boron nitrides-in both hexagonal and cubic mod